
Welcome to my Complete List of Publications, Patents, Meeting Abstracts, Workshops, Papers Presented, Poster Sessions and Unpublished Research Papers
Below are listed in chronological order, with hyperlinks, my chemistry research papers, meeting abstracts, theses, unpublished research papers and review papers archived on this web server.
A complete list including published papers and patents may also be found at http://jhm3.homestead.com/files/publicat.htm
Download freely any material of interest!
Journal Articles
1a. Tufts Undergraduate Thesis of Above Article
2. Alfred Viola and John H. MacMillan, Vapor Phase Thermolysis of 1-Hexen-5-yn-3-ol, An Acetylenic Oxy-Cope Reaction, J. Amer. Chem. Soc., Vol. 90, p6141, 1968. [700kB] :
4. Alfred Viola and John H. MacMillan, The Vapor Phase Acetylenic Oxy-Cope Reaction of 5-Hexen-1-yn-3-ol, The Chemistry of an Allenol Intermediate, J. Amer. Chem. Soc., Vol. 92, p2404, 1970. [1079kB] :
5. Alfred Viola, Robert J. Proverb, John H. MacMillan and Brian L. Yates, Participation of Acetylenic Bonds in Pericyclic Reactions , Thermal Cleavage of Beta-Hydroxyacetylenes, J. Amer. Chem. Soc., Vol. 93 p6967,1971. [1352kB] :
6. Alfred Viola, John H. MacMillan, Robert J. Proverb and Brian L. Yates, Reaction Rates by Flow System Thermolysis, The Competitive Components of the Oxy-Cope Reaction, Chemical Communications, p936, 1971. [232kB] :
7. Stephen S. Washburne and John H. MacMillan, Interaction of Carbonyl Compounds with Organometallic Azides, Part V., Sorboyl Chloride and its Conversion to an Alpha-Pyridone, J. Org. Chem., Vol. 38, p2982, 1973. [443kB] :
8. Stephen S. Washburne and John H. MacMillan, Lanthanide Chemical Shift Reagents as Tools for Determining Isomer Distributions in 2,4-Hexadiene-oates and Related Compounds, Organic Magnetic Resonance, Vol. 6., p250, 1974. [294kB] :
9. John H. MacMillan, Recent Examples of Selectivity in Catalysis, Strem Chemiker, Vol. 11, No. 2, July 1974. [1307kB]:
10. Stephen S. Washburne, James D. Warren and John H. MacMillan, Synthesis of Substituted 2H-1 3-Oxazine-2 6-Diones by Reaction of Trimethylsilyl Azide with Maleic Anhydrides, J.Org.Chem., Vol. 40, p 743, 1975. [556kB] :
11. Stephen S. Washburne and John H. MacMillan, Further Investigation of the Interaction of Trimethylsilyl Azide with Substituted Maleic Anhydrides, Synthesis of 4-and 5-Aryl Substituted 1,3-3H-Oxazine-2,6-Diones, J.Heterocyclic Chemistry, Vol. 12, p1215, 1975. [677kB] :
12. John H. MacMillan. Improved Procedure for the Preparation of Oxauracil 2H-1,3-3H-Oxazine-2,6-Dione, (Oxauracil), Organic Preparations and Procedures Int., Vol 9., p87, 1977. [198kB] :
13. M.M. Labes and John H. MacMillan, Low Transition Temperature Liquid Crystalline Amines Incorporating the Trans-1,4-Cyclohexane Ring System, Molecular Crystals and Liquid Crystals, Vol. 55, p61, 1979. [804kB] :
14. M.M. Labes and John H. MacMillan, Induced Phases in Terminal Mixtures of Polar Liquid Crystalline Amines and Nitriles, Mol. Crystals and Liquid Crystals Letters, Vol. 56, p7, 1979. [322kB] :
15. M.M. Labes and John H. MacMillan, Low Transition Temperature Liquid Crystalline Amines Incorporating the Biphenyl Ring System, Mol. Crystals and Liquid Crystals Letters, Vol. 56, p51, 1979. [394kB] :
16. John H. MacMillan " Oxidative dehydration of aryl substituted succinic acids with selenium dioxide; 4-Bromophenyl maleic anhydride".
17. John H. MacMillan "Nitrogen insertion reaction of trimethylsilyl azide with aryl substituted maleic anhydrides, yielding aryl substituted 1,3(3H) oxazine-2,6-diones; 4-(4-bromophenyl)-1,3(3H) oxazine-2,6-dione"
18. John H. MacMillan "Oxazine-2,6-dione N-methylation with dimethyl sulfate; N-Methyl-4-(4-methylphenyl)-1,3(3H)-oxazine-2,6-dione"
Chemspider January 16, 2012
19. John H. MacMillan and Alfred Viola, " Preparation of acetylenic alcohols by addition of propargyl Grignard reagents activated at low temperatures with mercury ion to a,ß-unsaturated aldehydes and ketones".
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20. John H. MacMillan "Addition of propargyl Grignard to aldehyde; 1-Phenyl-3-butyne-1-ol".
21. John H. MacMillan ”Addition of Allyl Magnesium Chloride to Propynal, 5-Hexen-1-yn-3-ol”
22. John H. MacMillan "Allyl Grignard addition to the internal alkyne carbon of propargyl alcohol; 2-Methylene-4-penten-1-ol"
DOI: http://dx.doi.org/10.1039/SP596
23. John H. MacMillan and Alfred Viola
“Mild Esterification with Diazomethane, Methyl-2E,4E-hexadienoate”
24. John H. MacMillan
"Nitrogen insertion
reaction of maleic anhydrides; 2-H-1,3-oxazine-2,6(3H)dione
Chemspider, December 5, 2013
25. John H. MacMillan
" Reduction of a benzonitrile; 1-[4-trans-4-Pentylcyclohexyl)phenyl]methanamine"
DOI: 10.1039/SP708
Chemspider, December 17, 2013
PDF (Internet archive), Introductory page
PDF (Homestead Archive)
PDF (Ccl.net Archive)
26. John H. MacMillan
"Partial hydrolysis of a benzonitrile 4-(trans-4-Pentylcyclohexyl)benzamide"
DOI: 10.1039/SP710
Chemspider, January 6, 2014
PDF (Internet archive), Introductory page
PDF (Homestead Archive)
PDF (Ccl.net Archive)
27. John H. MacMillan
"Hoffman degradation of benzamides to carbamates"
Internet Archive, December 2013
DOI: 10.1039/SP721
PDF (Internet archive), Introductory page
PDF (Homestead Archive)
PDF (Ccl.net Archive)
28.John H. MacMillan
DOI: 10.1039/SP725
U.S. Patents
1. M.M. Labes and John H. MacMillan, Amine Substituted Liquid Crystal Compositions, U.S. Patent 4,293,193, Oct. 6, 1981. [335kB] :
European patent Japanese Patent Canadian Patent
4. Michael J. Telepchak, Marla Marzinske, Thomas F. August, and John H. MacMillan, Method for the preparation of aminopropyl or aminoalkyl functional polyalkyl or aryl siloxanes, U.S. Patent 6, 177, 583, January 23, 2001. [347kB] :
5. Michael J. Telepchak, Wayne King, and John H. MacMillan, Siloxane modified carboxylic acid substituted amines and salts thereof, U.S. Patent 6, 489, 499, December 3, 2002. [479kB] :
6. Michael J. Telepchak, Ann N. Coyne and John H. MacMillan, Supported aldehydic silanes and method of manufacture, U.S. Patent 6, 589, 799, July 8, 2003. [446kB] :
7. Michael J. Telepchak, Ann N. Coyne, and John H. MacMillan, Supported aldehydic silanes and method of manufacture, U.S. Patent 7, 045, 365, May 16, 2006. [545kB] :
Foreign Translation
Japanese-Strem-Chemiker : Japanese Edition of "Recent Examples of Selectivity in Catalysis", by John H. MacMillan, Strem Chemicals, July,1, 1974.
Meeting abstracts, theses, unpublished research papers and review papers
2. A. Viola and J.H. MacMillan, "Addition of Grignard Reagents to Allylic and Propargylic Alcohols", J.H. MacMillan, Ph.D. Thesis, Northeastern University, 1970.
4. John H. MacMillan and Stephen S. Washburne, "Further Studies of the Interaction of Carbonyl Compounds with Organometallic Azides, the Novel Reaction of Benzoquinone with Trimethylsilyl Azide", Report of Investigators to the National Cancer Institute, 1972.
5. J.H. MacMillan, "Recent Examples of Selectivity in Catalysis" Strem Chemiker, Vol. 11 No. 2, July 1974.
6. J. H. MacMillan, M. E. Strem, F. A. Fowler and George Guy, "An Improved Method for the Preparation of Bis-DiphenylPhosphino Acetylene and unsymmetrical Aryl Substituted Diphenylphosphino Acetylenes", Strem Chemiker, Vol. 11, No. 2, July 1974.
7. Mark Lenhart, John H. MacMillan, Alice Maragliano and Steven S. Washburne, "A Facile General Synthesis of Aryl Maleic Anhydrides", Temple University, 1976. Presented at the 10th Middle Atlantic Regional Meeting of the American Chemical Society Philadelphia Pa. February, 1976, Paper # 10, Undergraduate research.
8. John H. MacMillan and Stephen S. Washburne, "Hydrolysis reactions of the 4-and 5-Alkyl or Aryl Substituted 1,3(3H) Oxazine-2,6-Dione (Oxauracil) Ring System", Temple University, 1977, Report to the U.S. Army Medical Research and Development command; Grant Number DAMD 17-74-C4100.
9. J.H. MacMillan and M.M. Labes, "Synthesis and Photochemistry of Chiral Liquid Crystalline Nitrones", Poster Session Gordon Research Conference, Liquid Crystals Santa Barbara, California, January, 1980.
10. E.R. Bertozzi and John H. MacMillan, "Hexamethylene Glycol Polyformal Copolymers for Insulating Glass and Building Sealants", Thiokol Corporation, Company Private, Sept 15, 1980.
Beaver College (Arcadia University), 1992.
12. John H. MacMillan,"Virtual Chemistry Laboratory for Non-Science Majors, Good or Bad?"
Beaver College (Arcadia University), 1995
13. John H. MacMillan, "Using Silanes as Adhesion Promoters", United Chemical Technologies Technical Workshop, 1997, Presented at 214th Meeting of the American Chemical Society, Los Vegas, Nevada 1997, and the 215th Meeting of the American Chemical Society, Dallas ,Texas , 1998.
14. John H. MacMillan, United Chemical Technologies Technical Workshop."Formulating Silicone Adhesives, Rubbers and Gels" 1998.
Presented at the 220th National Meeting of the American Chemical Society, Washington, D.C. 2000.
15. John H. MacMillan, " Silane Surface Modifying Reagents", United Chemical Technologies Technical Workshop, 1999.
17. John H. MacMillan "Homogeneous Platinum Catalysts", United Chemical Technologies Technical Workshop, Presented at the 222nd National Meeting of the American Chemical Society, Chicago, llinois, 2001.
18. John H. MacMillan "Mnemonic use for aiding students to determine erythro vs threo stereochemistry in additions to internal alkenes”
Temple University chemistry instructional aid, 2013
Temple University, chemistry instructional aid, 2013.
PDF (Ccl.net)
20. John Harry MacMillan
Chemspider structure depositions, September-November 2013 (Homestead).
PDF (Ccl.net)
21. John H. MacMillan and Alfred Viola
“Mild Esterification with Diazomethane, Methyl-2E,4E-hexadienoate”
22. John H. MacMillan and Alfred Viola
"Reduced pressure oxidation of propargyl alcohol to aldehyde, Propynal"
November , 2013
23. John H. MacMillan and Alfred Viola
(Google Archive, 2013)
24. John H. MacMillan
"Nitrogen insertion
reaction of maleic anhydrides; 2-H-1,3-oxazine-2,6(3H)dione
Chemspider, December 5, 2013
25. John H. MacMillan
"Basic hydrolysis of methyl carbamates to amines"
Internet Archive, January 2014
PDF (Internet archive), Introductory page
PDF (Homestead Archive)
John H. MacMillan
"Secondary amides from anilines: N-[4-(trans-4-Heptylcyclohexyl)phenyl]heptanamide"
Internet Archive, January 2014
PDF (Internet archive), Introductory page
PDF (Homestead Archive)
PDF (Ccl.net Archive)
"Aromatic secondary amines from aromatic amides"
Internet Archive, January 2014
PDF (Internet archive), Introductory page
PDF (Homestead Archive)
PDF (Ccl.net Archive)
28. John H. MacMillan
"Borch synthesis of secondary amines from aromatic nitriles"
Internet Archive, January 2014
PDF (Internet archive), Introductory page
PDF (Homestead Archive)
PDF (Ccl.net Archive)
Undergraduate, Ph.D. Theses
1) Tufts University Undergraduate Thesis, 1966.
a) Line Broadening in the X-Ray diffraction patterns for the Vanadium Hydride System
b) The Magnetic Susceptibility of Palladium Hydride
2) Northeastern University, Ph.D. Thesis, 1970.
"Triple Bond Participation in the Oxy-Cope "Rearrangement"
PDF (Retyped, Google document)
PDF (Yolasite)
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Addition_of_Allyl_Magnesium_Chloride_to_Propynal-published-12-20-12.pdf Size : 112.073 Kb Type : pdf |
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constructivist.pdf Size : 154.668 Kb Type : pdf |
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virtual-laboratory.pdf Size : 115.136 Kb Type : pdf |
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patent1.pdf Size : 335.296 Kb Type : pdf |
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patent7.pdf Size : 544.665 Kb Type : pdf |
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acetylenes.pdf Size : 944.109 Kb Type : pdf |
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adhesion.pdf Size : 407.961 Kb Type : pdf |
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ArylMaleic-Anhydrides.pdf Size : 2184.607 Kb Type : pdf |
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bioconext.pdf Size : 41.941 Kb Type : pdf |
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chemiker.pdf Size : 1306.895 Kb Type : pdf |
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diphenylacetylene2.pdf Size : 400.702 Kb Type : pdf |
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formulating.pdf Size : 2866.547 Kb Type : pdf |
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Grignard-addition-to-propargylic-allylic-alcohols.pdf Size : 1467.042 Kb Type : pdf |
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Japanese-Strem-Chemiker-1974.pdf Size : 5654.259 Kb Type : pdf |
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Nitrones-2.pdf Size : 3075.961 Kb Type : pdf |
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Oxauracils-Hydrolysis.pdf Size : 4902.953 Kb Type : pdf |
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Palladium-hydride.pdf Size : 4264.15 Kb Type : pdf |
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platinum.pdf Size : 1587.421 Kb Type : pdf |
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surface.pdf Size : 38.03 Kb Type : pdf |
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tmsa-benzoquinone-4.pdf Size : 818.511 Kb Type : pdf |
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Vanadiun-Line-Broadening.pdf Size : 3002.897 Kb Type : pdf |
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Thesis.pdf Size : 7265.125 Kb Type : pdf |
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phd.pdf Size : 13015.878 Kb Type : pdf |
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aryl-oxauracils.pdf Size : 45.5 Kb Type : pdf |
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napthoquinones-trimethylsilyl azide.pdf Size : 53.078 Kb Type : pdf |
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phenyl.pdf Size : 1214.933 Kb Type : pdf |
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