Welcome  to my Complete  List of Publications, Patents, Meeting Abstracts, Workshops, Papers Presented, Poster Sessions  and Unpublished Research Papers  

 

Below are listed in chronological order, with hyperlinks, my chemistry research papers, meeting abstracts, theses, unpublished research papers and review papers archived on this web server.

 A complete list including published papers and patents may also  be found  at http://jhm3.homestead.com/files/publicat.htm

Download  freely any material of interest!


   Journal Articles

1. Thomas R.P. Gibb Jr., Richard J. Roy, and John H. MacMillan, The Magnetic Susceptibility of Palladium Hydride J. Phys. Chem., Vol. 70, p3024, 1966. [114kB] :

1a. Tufts Undergraduate Thesis of Above Article


  2.  Alfred Viola and John H. MacMillan, Vapor Phase Thermolysis of 1-Hexen-5-yn-3-ol, An  Acetylenic Oxy-Cope Reaction,  J. Amer. Chem. Soc.,   Vol. 90, p6141, 1968. [700kB] :


  3. Alfred Viola and John H. MacMillan, A Novel Steric Effect in the Thermolysis of Prop-2-ynyl Vinyl Carbinols, Chemical Communications, p301,1970. [200kB] :


4. Alfred Viola and John H. MacMillan, The Vapor Phase Acetylenic Oxy-Cope Reaction  of 5-Hexen-1-yn-3-ol, The Chemistry of an Allenol Intermediate,  J. Amer. Chem. Soc., Vol. 92, p2404, 1970. [1079kB] :


 5. Alfred Viola, Robert J. Proverb, John H. MacMillan and Brian L. Yates, Participation of Acetylenic Bonds in Pericyclic  Reactions , Thermal Cleavage of Beta-Hydroxyacetylenes,  J. Amer. Chem. Soc., Vol. 93 p6967,1971. [1352kB] :

 


 6. Alfred Viola, John H. MacMillan, Robert J. Proverb and Brian L. Yates, Reaction Rates by Flow System Thermolysis,  The Competitive Components of the Oxy-Cope Reaction,  Chemical Communications, p936, 1971. [232kB] :

 


 7. Stephen S. Washburne and John H. MacMillan, Interaction of Carbonyl Compounds with Organometallic  Azides, Part V., Sorboyl Chloride and its Conversion to an Alpha-Pyridone,  J. Org. Chem., Vol. 38, p2982, 1973. [443kB] :


 8. Stephen S. Washburne and John H. MacMillan, Lanthanide Chemical Shift Reagents as Tools for Determining Isomer Distributions in 2,4-Hexadiene-oates and Related Compounds,  Organic Magnetic Resonance, Vol. 6., p250, 1974. [294kB] :

 


  9. John H. MacMillan, Recent Examples of Selectivity in Catalysis, Strem   Chemiker, Vol. 11, No. 2, July 1974. [1307kB]: 


10. Stephen S. Washburne, James D. Warren and John H. MacMillan, Synthesis of Substituted 2H-1 3-Oxazine-2 6-Diones  by Reaction of Trimethylsilyl Azide with   Maleic Anhydrides,  J.Org.Chem., Vol. 40, p 743, 1975. [556kB] :


11. Stephen S. Washburne and John H. MacMillan, Further Investigation of the Interaction of Trimethylsilyl Azide  with Substituted Maleic Anhydrides, Synthesis of 4-and 5-Aryl  Substituted 1,3-3H-Oxazine-2,6-Diones,  J.Heterocyclic Chemistry, Vol. 12,  p1215, 1975. [677kB] :


 12. John H. MacMillan. Improved Procedure for the Preparation of Oxauracil 2H-1,3-3H-Oxazine-2,6-Dione, (Oxauracil),  Organic Preparations and Procedures Int., Vol 9., p87, 1977. [198kB] :


 13. M.M. Labes and John H. MacMillan, Low Transition Temperature Liquid Crystalline Amines Incorporating  the Trans-1,4-Cyclohexane Ring System,   Molecular Crystals and Liquid Crystals, Vol. 55, p61, 1979. [804kB] :


  14. M.M. Labes and John H. MacMillan, Induced Phases in Terminal Mixtures of Polar Liquid Crystalline Amines  and Nitriles, Mol. Crystals and Liquid Crystals Letters, Vol. 56, p7, 1979. [322kB] :

 


  15. M.M. Labes and John H. MacMillan, Low Transition Temperature Liquid Crystalline Amines Incorporating  the Biphenyl Ring System,  Mol. Crystals and Liquid Crystals Letters, Vol. 56, p51, 1979. [394kB] :  

  


 

            

16. John H. MacMillan " Oxidative dehydration of aryl substituted succinic acids with selenium dioxide; 4-Bromophenyl maleic anhydride".

Chemspider, January 5, 2012

PDF


17.  John H. MacMillan "Nitrogen insertion reaction of trimethylsilyl azide with aryl substituted maleic anhydrides, yielding aryl substituted 1,3(3H) oxazine-2,6-diones; 4-(4-bromophenyl)-1,3(3H) oxazine-2,6-dione"

Chemspider January 16, 2012

PDF


18.  John H. MacMillan "Oxazine-2,6-dione N-methylation with dimethyl sulfate; N-Methyl-4-(4-methylphenyl)-1,3(3H)-oxazine-2,6-dione"

Chemspider January 16, 2012

PDF

 


19.  John H. MacMillan and Alfred Viola, " Preparation of acetylenic alcohols by addition of propargyl  Grignard reagents activated at low temperatures with mercury ion to a,ß-unsaturated aldehydes and ketones".


20.  John H. MacMillan "Addition of propargyl Grignard to aldehyde; 1-Phenyl-3-butyne-1-ol".

Chemspider February 17, 2012

PDF


21. John H. MacMillan ”Addition of Allyl Magnesium Chloride to Propynal, 5-Hexen-1-yn-3-ol”

Chemspider December 20, 2012

PDF

Google doc


22. John H. MacMillan "Allyl Grignard addition to the internal alkyne carbon of propargyl alcohol; 2-Methylene-4-penten-1-ol"

DOI: http://dx.doi.org/10.1039/SP596

 Chemspider June 7, 2013

PDF

Google Doc

PDF (Ccl.net)


23. John H. MacMillan  and Alfred Viola

“Mild Esterification with Diazomethane, Methyl-2E,4E-hexadienoate”

 

Chemspider November 13, 2013

DOI: 10.1039/SP701

Google Document

Homestead Archive

Ccl.net Archive

Internet Archive


24. John H. MacMillan

"Nitrogen insertion reaction of maleic anhydrides; 2-H-1,3-oxazine-2,6(3H)dione"

Chemspider, December 5, 2013

DOI 10.1039/SP707

Google Archive

Internet Archive

Ccl.net Archive

Homestead Archive



25. John H. MacMillan

" Reduction of a benzonitrile; 1-[4-trans-4-Pentylcyclohexyl)phenyl]methanamine"

DOI: 10.1039/SP708

Chemspider, December 17, 2013

Google Archive

PDF (Internet archive), Introductory page

PDF (Homestead Archive)

PDF (Ccl.net Archive)


26. John H. MacMillan

"Partial hydrolysis of a benzonitrile 4-(trans-4-Pentylcyclohexyl)benzamide"

DOI: 10.1039/SP710

Chemspider, January 6, 2014

Google Archive 

PDF (Internet archive), Introductory page

PDF (Homestead Archive)

PDF (Ccl.net Archive)


27. John H. MacMillan

"Hoffman degradation of benzamides to carbamates"

Internet Archive, December 2013

Google Archive

Chemspider February 27, 2014

DOI: 10.1039/SP721

PDF (Internet archive), Introductory page

PDF (Homestead Archive)

PDF (Ccl.net Archive)


28.John H. MacMillan


"Diacetylenic alcohols by in situ Grignard reaction with acetylenic aldehydes or ketones; 3-methyl-1,5-hexadiyn-3-ol"

 

Internet Archive, March 2014

 

Google Archive

 

Ccl.net Archive

 

Homestead Archive

PDF

Chemspider March 12, 2014

 

DOI: 10.1039/SP725




                         U.S. Patents

1. M.M. Labes and John H. MacMillan, Amine Substituted Liquid Crystal Compositions,  U.S. Patent 4,293,193, Oct. 6, 1981. [335kB] :


 2. Eugene R. Bertozzi, Bruce E. Streeter, and John H. MacMillan, One Package Heat Curable Sealant Compositions,  U.S. Patent 4,430,489, Feb. 7, 1984. [762kB] :

European patent    Japanese Patent   Canadian Patent


3. Eugene R. Bertozzi, Bruce E. Streeter, and John H. MacMillan, Thioether Modified Polymer Compositions,  U.S. Patent 4,590, 240, May 20, 1986. [530kB] :

European Patent


 4. Michael J. Telepchak, Marla Marzinske, Thomas F. August, and John H. MacMillan, Method for the preparation of aminopropyl  or aminoalkyl functional polyalkyl or aryl siloxanes, U.S.  Patent 6, 177, 583, January 23, 2001. [347kB] :


5. Michael J. Telepchak, Wayne King, and John H. MacMillan, Siloxane modified carboxylic acid  substituted amines and salts thereof, U.S.  Patent 6, 489, 499, December 3, 2002. [479kB] :


6. Michael J. Telepchak, Ann N. Coyne and John H. MacMillan, Supported aldehydic silanes and method of manufacture,  U.S. Patent 6, 589, 799, July 8, 2003. [446kB] :


7. Michael J. Telepchak, Ann N. Coyne, and John H. MacMillan, Supported aldehydic silanes and method of manufacture,  U.S. Patent 7, 045, 365, May 16, 2006. [545kB] :


                  Foreign Translation

Japanese-Strem-Chemiker : Japanese Edition of "Recent Examples of Selectivity in Catalysis", by John H. MacMillan, Strem Chemicals, July,1, 1974.


3. A. Viola and J.H. MacMillan, "Vapor Phase Thermolysis of 1,5-Hexadiynes, Effect of Hydroxyl Substitution". Presented at the 159th National Meeting of the American Chemical Society Houston Texas, February 1970, Abstract # ORGN 50. 


  4. John H. MacMillan and Stephen S. Washburne, "Further Studies of the Interaction of Carbonyl Compounds with Organometallic    Azides, the Novel Reaction of Benzoquinone with Trimethylsilyl Azide", Report of Investigators to the National Cancer Institute, 1972.


5. J.H. MacMillan, "Recent Examples of Selectivity in Catalysis" Strem Chemiker, Vol. 11 No. 2, July 1974.


 6. J. H. MacMillan, M. E. Strem, F. A. Fowler and George Guy, "An Improved   Method for the Preparation of Bis-DiphenylPhosphino Acetylene and unsymmetrical Aryl Substituted Diphenylphosphino Acetylenes", Strem Chemiker, Vol. 11, No. 2, July 1974.


 7. Mark Lenhart, John H. MacMillan, Alice Maragliano and Steven S. Washburne, "A Facile General Synthesis of Aryl Maleic Anhydrides", Temple University, 1976. Presented at the 10th Middle Atlantic Regional Meeting of the American Chemical Society Philadelphia Pa. February, 1976, Paper # 10, Undergraduate research.


8. John H. MacMillan and Stephen S. Washburne, "Hydrolysis reactions of the 4-and 5-Alkyl or Aryl Substituted 1,3(3H) Oxazine-2,6-Dione (Oxauracil) Ring System",  Temple University, 1977, Report to the U.S. Army Medical Research and Development command; Grant Number DAMD 17-74-C4100.


     9. J.H. MacMillan and M.M. Labes, "Synthesis and Photochemistry of Chiral Liquid Crystalline Nitrones", Poster Session Gordon Research Conference, Liquid Crystals Santa Barbara, California, January, 1980.

 


  10. E.R. Bertozzi and John H. MacMillan, "Hexamethylene Glycol Polyformal Copolymers for Insulating Glass and Building Sealants", Thiokol Corporation, Company Private, Sept 15, 1980.

 


 11. John H. MacMillan, "Is a Totally Constructivist Approach to the Teaching of High School Chemistry Possible in Practice"?

Beaver College (Arcadia University), 1992.


 12. John H. MacMillan,"Virtual Chemistry Laboratory for Non-Science Majors, Good or Bad?"

Beaver College (Arcadia University), 1995 


 13. John H. MacMillan, "Using Silanes as Adhesion Promoters", United Chemical Technologies Technical Workshop, 1997, Presented at 214th Meeting of the American Chemical Society, Los Vegas, Nevada 1997, and the 215th Meeting of the American Chemical Society, Dallas ,Texas , 1998.

 


  14. John H. MacMillan, United Chemical Technologies Technical Workshop."Formulating Silicone Adhesives, Rubbers and Gels" 1998.                                        

    Presented at the 220th National Meeting of the American Chemical Society, Washington, D.C. 2000.


15. John H. MacMillan, " Silane Surface Modifying Reagents", United Chemical Technologies Technical Workshop, 1999.


 16. John H. MacMillan "A method for derivatizing surfaces with aldehyde groups by employing a new alkoxy aldehydic silane", Coyne, Ann N., Benner, Lauren., MacMillan, John H., Telepchak, Michael T, United Chemical Technologies, technical publication, 2001.


  17. John H. MacMillan "Homogeneous Platinum Catalysts", United Chemical Technologies Technical Workshop, Presented at the 222nd National Meeting of the American Chemical Society, Chicago, llinois, 2001.

 18. John H. MacMillan "Mnemonic use for aiding students to determine erythro vs threo stereochemistry in additions to internal alkenes”

Temple University chemistry instructional aid, 2013

 

Google Doc

 PDF

PDF (ccl.net)


19. John H. MacMillan “Reagent Code Lists for Aiding Beginning Students in Determining the Structure of an Organic Chemistry Reaction Product.”

Temple University, chemistry instructional aid, 2013.

Google Document

PDF

PDF (Ccl.net)

PDF(Homestead)


20. John Harry MacMillan 

Chemspider structure depositions, September-November 2013 (Homestead).

PDF (Ccl.net)

 


21. John H. MacMillan  and Alfred Viola

“Mild Esterification with Diazomethane, Methyl-2E,4E-hexadienoate”

 

Chemspider November 13, 2013

DOI: 10.1039/SP701

Google Document

Homestead Archive

Ccl.net Archive


22. John H. MacMillan  and Alfred Viola

"Reduced pressure oxidation of propargyl alcohol to aldehyde,  Propynal"

November , 2013

Homestead archive

Internet Archive


23. John H. MacMillan  and Alfred Viola

"Formation of 1-cyclopent-1-ylcarbinols from the reaction of excess allylmagnesium chloride with acetylenic alcohols"

(Google Archive, 2013)

Internet archive, 2013 (link)

Ccl.net Archive (link)


24. John H. MacMillan

"Nitrogen insertion reaction of maleic anhydrides; 2-H-1,3-oxazine-2,6(3H)dione"

Chemspider, December 5, 2013

DOI 10.1039/SP707

Google Archive

Internet Archive


25. John H. MacMillan

"Basic hydrolysis of methyl carbamates to amines"

Internet Archive, January 2014

Google Archive

PDF (Internet archive), Introductory page

PDF (Homestead Archive)

PDF (Ccl.net Archive)


26.

John H. MacMillan

"Secondary amides from anilines: N-[4-(trans-4-Heptylcyclohexyl)phenyl]heptanamide"

Internet Archive, January 2014

Google Archive

PDF (Internet archive), Introductory page

PDF (Homestead Archive)

PDF (Ccl.net Archive)


27.  John H. MacMillan

"Aromatic secondary amines from aromatic amides"

Internet Archive, January 2014

Google Archive

PDF (Internet archive), Introductory page

PDF (Homestead Archive)

PDF (Ccl.net Archive)


28. John H. MacMillan

"Borch synthesis of secondary amines from aromatic nitriles"

Internet Archive, January 2014

Google Archive

PDF (Internet archive), Introductory page

PDF (Homestead Archive)

PDF (Ccl.net Archive)




Undergraduate, Ph.D. Theses

1) Tufts University Undergraduate Thesis, 1966.

a) Line Broadening in the X-Ray diffraction patterns for the Vanadium Hydride System

b) The Magnetic Susceptibility of Palladium Hydride


 

2) Northeastern University, Ph.D. Thesis, 1970.

"Triple Bond Participation in the Oxy-Cope "Rearrangement"

PDF (Retyped, Google document)

PDF (Yolasite)


 

 

 

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